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It's a brilliant opportunity to sell yourself and qualify those who may be a potential match. You can add a photo of yourself and get searching for profiles, interests and matches! Send an ice breaker message and your online dating journey has started! It really is as easy as that! The detection limit for all major element oxides was 0. For minor and trace elements the detection limits varied between 0. The potassium and argon analyses were undertaken at Geochron Laboratories under the direction of Richard Reesman, the K-Ar laboratory manager. No specific location or expected age information was supplied to the laboratory.
However, the samples were described as andesites that probably contained "low argon" and therefore could be young, so as to ensure the laboratory took extra care with the analytical work. Because the sample pieces were submitted as whole rocks, the K-Ar laboratory undertook the crushing and pulverising preparatory work. The 40 K concentrations ppm were calculated from the terrestrial isotopic abundance using the measured concentrations of K 2 O. Clark [11] reported that most of the flows from Ngauruhoe are labradorite-pyroxene andesite with phenocrysts of plagioclase labradorite , hypersthene and rare augite in a hyalopilitic needle-like microlites set in a glassy mesostasis groundmass containing abundant magnetite.
However, all lava, lapilli and incandescent blocks that have been analysed from eruptions this century also contain olivine; chemically they may be classed as low-silica or basaltic andesites using the classification scheme of Gill [36]. The published analyses in Table 1 show only trivial changes in composition between and In fact, the and andesites are so similar that Nairn et al. This plug was disrupted and blown from the vent as ejecta ranging in texture from solid blocks, through expanded scoria to spatter bombs.
Table 2 lists the whole-rock major element analyses of the eleven samples collected in this study. Comparison of the data for each flow with the corresponding data in Table 1 indicates that in their bulk chemistries all the samples analyzed and thus all the flows are virtually identical to one another, the trivial differences being attributable to the statistics of analytical errors, sampling and natural variations. Thus it is not unreasonable to conclude that these basaltic andesites are cogenetic, coming from the same magma and magma chamber, even as they have been observed to flow from the same volcano.
Ejecta from March eruption [11,46] 2. Lava from February eruption [11, 46, 90] 3. Lava from June 30, flow [11, 27, 90] 4.
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Average of four lava flows from eruptions [46, 70] 7. Average of five blocks and bombs from January and March eruptions [46, 70] 8. Whole-rock, major-element oxide analyses of recent lava flows at Mt Ngauruhoe, New Zealand, as reported in the literature. Nevertheless, Nairn et al. However, these trends are not duplicated with any statistical significance by the analytical results of this study Table 2. At least they found that their analyses of the lava blocks and bombs were identical within the limits of error with the lava Table 1 , which was also substantiated in this study with respect to the avalanche material and the lava Table 2.
Clark [11] and Cole [12] recognized five lava types in the Tongariro Volcanic Center based on the modal proportions of the phenocryst minerals.
Graham [37] modified this scheme to six types based on a combination of mineralogy and chemistry, but given their uniform bulk chemistry and petrology, these Ngauruhoe lava flows group together as plagioclase-pyroxene andesite within Graham's -Type Cole et al. They are relatively Fe-rich and follow a typical calc-alkaline trend on the AFM diagram. February 11, flow, samples A and B 2. June 4, flow, samples A and B 3. June 30, flow, samples A, B and C 4.
July 14, flow, samples A and B 5. Their designation as plagioclase-pyroxene andesites is based on the predominant phenocrysts present, with plagioclase greater than or equal to pyroxene. Two modal analyses are listed in Table 3 which very closely resemble the samples collected for this study. Ngauruhoe VU [15], a flow. Olivine-bearing low-Si andesite, June 30, Ngauruhoe flow [12]. Table 3. Modal analyses of two recent lava flows at Mt Ngauruhoe, New Zealand, as reported in the literature.
The phenocryst assemblage is dominated by plagioclase, but orthopyroxene and augite clinopyroxene are always major components, while olivine and magnetite are only present in trace amounts. This POAM phenocryst assemblage is a typical anhydrous mineralogy [15]. Steiner [90] stressed that xenoliths are a common constituent of the Ngauruhoe lava, but also noted that Battey [7] reported the Ngauruhoe lava was rich in xenoliths. All samples in this study contained xenoliths, including those from the avalanche material.
However, many of these aggregates are more accurately described as glomerocrysts and mafic gabbro, websterite nodules [39]. They are mm across, generally have hypidiomorphic-granular textures, and consist of plagioclase, orthopyroxene and clinopyroxene in varying proportions, and very occasionally olivine. The true xenoliths are often rounded and invariably consist of fine quartzose material. Steiner [90] also described much larger xenoliths of quartzo-feldspathic composition and relic gneissic structure.
The plagioclase phenocrysts have been reported as ranging in composition from An 89 to An 40 andesine to bytownite , but in Ngauruhoe lavas are usually labradorite An They are subhedral and commonly exhibit complex oscillatory zoning with an overall trend from calcic cores to sodic rims [12, 14, 15]. Thin outer rims are usually compositionally similar to groundmass microlites. Twinning and hourglass structures are common. Subhedral-euhedral orthopyroxene is typically pleochroic and sometimes zoned. Compositions range from Ca 4 Mg 74 Fe 22 to Ca 3 Mg 47 Fe 50 [14, 15], but representative bulk and partial analyses of Ngauruhoe orthopyroxenes [12, 26, 38] indicate a hypersthene composition predominates, which is confirmed by optical determinations [11, 12].
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Euhdral-subhedral clinopyroxene is typically twinned and zoned, but compositions show a restricted range of Ca 43 Mg 47 Fe 10 to about Ca 35 Mg 40 Fe 25 , all of which is augite [15, 39]. The olivine present is strongly magnesian, analyses indicating some compositional zoning from Fo 88 to Fo The magnetite present in the groundmass is titanomagnetite, judging from the amount of TiO 2 present in whole-rock analyses Tables 1 and 2 , but some ilmenite is likely to occur sporadically in association with it [15, 39].
All analytical results received from Geochron Laboratories are listed in Table 4, grouped in chronological order according to the historic date of each flow.